Nucleophilic substitution at the central allyl carbon atom of a (.pi.-allyl)platinum complex
β Scribed by Ohe, Kouichi; Matsuda, Hideki; Morimoto, Tsumoru; Ogoshi, Sensuke; Chatani, Naoto; Murai, Shinji
- Book ID
- 127057648
- Publisher
- American Chemical Society
- Year
- 1994
- Tongue
- English
- Weight
- 253 KB
- Volume
- 116
- Category
- Article
- ISSN
- 0002-7863
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48 h gave the saturated silanes 21,23, and 25 in greater than 90 % yields. Exceptionally high diastereoselectivities (> 500: 1) were noted in all cases. No desilylation was observed under these conditions. Table . Directed hydrogenation of y-hydroxyvinylsilanes. The substrate was treated with 5 mol