Nucleophilic substitution at phosphoryl phosphorus
โ Scribed by C.R. Hall; D.J.H. Smith
- Publisher
- Elsevier Science
- Year
- 1974
- Tongue
- French
- Weight
- 209 KB
- Volume
- 15
- Category
- Article
- ISSN
- 0040-4039
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๐ SIMILAR VOLUMES
The reaction of alkyllithium reagents with tertiary phosphines has been investigated by a number of groups.' These reactions have involved the deprotonation of an aryl ring,latb mthyl,'b\*c\*d~e or bensyllfrg groups attached to
Reactions of 3-acetoxy-3,5,5-trimethyl-1,2,4-trioxolane (z) with methanol, benzyl alcohol or phenol gave the corresponding ether ozonldes z -e. Reaction of 2 with benzyl alcohol and with acetate ion gave 5d and 2, respectfiely. -The known reactions of nucleophiles with ozonides 1 occur either by att
## Reactions of one diastereomer of a )P-NMe2 compound (La) with alcohols, phenol and amines have been shown by NMR to proceed with initial inversion at phosphorus, but the overall reactions are not stereoselective.