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Nucleophilic substitution at an sp2 carbon of vinyl halides with an intramolecular thiolate moiety: synthesis of 2-alkylidenethietanes

โœ Scribed by Mao-Yi Lei; Koji Fukamizu; Yong-Jun Xiao; Wei-Min Liu; Scott Twiddy; Shunsuke Chiba; Kaori Ando; Koichi Narasaka


Book ID
108284985
Publisher
Elsevier Science
Year
2008
Tongue
French
Weight
323 KB
Volume
49
Category
Article
ISSN
0040-4039

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## Abstract 2โ€Aryl(arylsulfonyl)โ€6,7โ€dihydroโ€2__H__โ€imidazo[2,1โ€__c__][1,2,4]triazolโ€3(5__H__)โ€ones and 3โ€aryliminoโ€6,7โ€dihydroimidazo[2,1โ€__c__][1,2,4]thiadiazoles have been synthesized by intramolecular nucleophilic substitution reactions at the electronโ€deficient sp^2^ nitrogen atom of 2โ€(hydrox