✦ LIBER ✦
Nucleophilic substitution at an acetylenic carbon: 1-alkoxy-2-phenylacetylenes from 1-chloro-2-phenylacetylene
✍ Scribed by Ryuichi Tanaka; Sidney I. Miller
- Publisher
- Elsevier Science
- Year
- 1971
- Tongue
- French
- Weight
- 193 KB
- Volume
- 12
- Category
- Article
- ISSN
- 0040-4039
No coin nor oath required. For personal study only.
✦ Synopsis
The usual routes to acetylenic ethers, e.g. from acetylenes, aldehydes, or vinyl ethers, involve many steps (1). Here we describe a short route to phenylalkoxyacetylenes q) from phenylacetylene via phenylchloroacetylene (,l,): nucleophilic attack on 1 by some alkoxides