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Nucleophilic Substitution at a Saturated Carbon Atom.

✍ Scribed by Bartlett, Paul D.


Book ID
126063376
Publisher
American Chemical Society
Year
1964
Tongue
English
Weight
154 KB
Volume
86
Category
Article
ISSN
0002-7863

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Nucleophilic substitution at a saturated
✍ Johann Gasteiger; Karlheinz Kaufmann; Christian Herzig; T.William Bentley πŸ“‚ Article πŸ“… 1985 πŸ› Elsevier Science 🌐 French βš– 195 KB

Whereas reaction of trans-2-chloro or 2-bromo-3-tert-butyloxirane with thiophenc Zate occuΓ―>s at C-3 to gi7>e 2-phenylmercapto-3,3-dimethyZbutanaZ,phenoZates give substitution at C-2 witk retention of tke oxirane ring and retention of configuration witk kinetics tkat indicate a bimoZecuZar meckanism