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Nucleophilic reactivity: nucleophilic aromatic substitution reactions of 2,4-dinitrochlorobenzene and picryl chloride in aqueous and methanol solutions

✍ Scribed by Gandler, Joseph R.; Setiarahardjo, Irianto U.; Tufon, Chrisanthus; Chen, Chinpan


Book ID
120350494
Publisher
American Chemical Society
Year
1992
Tongue
English
Weight
655 KB
Volume
57
Category
Article
ISSN
0022-3263

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Reaction kinetics of 1-chloro-2,4-dinitrobenzene with piperidine was studied spectrophotometrically in aqueous solutions of methanol, ethanol, and propan-2-ol at 25ЊC. The reaction in these solutions is not catalyzed by piperidine. The plots of second-order rate constants of the reaction vs. mole fr