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Nucleophilic Reactivities of Ketene Acetals

✍ Scribed by Takahiro Tokuyasu; Herbert Mayr


Publisher
John Wiley and Sons
Year
2004
Tongue
English
Weight
155 KB
Volume
2004
Category
Article
ISSN
1434-193X

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The relationship between the relative reactivities of ten cyclic ketene acetals and their structures was determined via cationic copolymerizations of eight different monomer pairs. Thus, 2-methylene-1,3-dioxolane (1) was copolymerized with 2-methylene-4-methyl-1,3-dioxolane (2), 2-methylene-4,5-dime

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## Abstract The kinetics of the reactions of azulene (**1**), 6,6‐dimethylfulvene (**2**), 6‐[4‐(dimethylamino)phenyl]fulvene (**3**) and 6‐(julolidin‐9‐yl)fulvene (**4**) with a set of benzhydrylium ions (reference electrophiles) have been investigated in MeCN. The second‐order rate constants for