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Nucleophilic Displacement Reactions in Aromatic Systems. VIII. Rates and Mechanism for the Reaction of 2,4-Dinitrochlorobenzene with 1,4-Diazabicyclo[2.2.2]octane in Acetonitrile

✍ Scribed by Ross, Sidney D.; Bruno, John J.; Petersen, Raymond C.


Book ID
120350464
Publisher
American Chemical Society
Year
1963
Tongue
English
Weight
588 KB
Volume
85
Category
Article
ISSN
0002-7863

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Rate constants for the gas-phase reactio
✍ R. Koch; H-U. KrΓΌger; M. Elend; W-U. Palm; C. Zetzsch πŸ“‚ Article πŸ“… 1996 πŸ› John Wiley and Sons 🌐 English βš– 493 KB πŸ‘ 2 views

The title compounds were selected to test the current predictions of OH reaction rate constants The reactions are studied employing flash photolysis/resonance fluorescence in 130 rnbar He at room temperature and up to 420 K. Experimental difficulties were encountered due to the polar and hygroscopic