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Nucleophilic character of acyl radicals. Substituent effects on the homolytic acylation of protonated heteroaromatic bases

✍ Scribed by Caronna, T.; Fronza, G.; Minisci, F.; Porta, O.; Gardini, G. P.


Book ID
120041389
Publisher
Royal Society of Chemistry
Year
1972
Tongue
English
Weight
601 KB
Volume
10
Category
Article
ISSN
1472-779X

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## Abstract A new process for the homolytic acylation of protonated heteroaromatic bases is described; an N‐oxyl radical (PINO) generated from __N__‐hydroxyphthalimide by air oxygen and Co(II) abstracts a hydrogen atom from an aldehyde. The resulting nucleophilic acyl radical adds to a heteroaromat