Nucleophilic catalysis of phosphorus trichloride oxygen oxidation
β Scribed by Ludmila V. Bezgubenko; Sergey E. Pipko; Alexandr A. Shalimov; Anatoliy D. Sinitsa
- Publisher
- John Wiley and Sons
- Year
- 2008
- Tongue
- English
- Weight
- 105 KB
- Volume
- 19
- Category
- Article
- ISSN
- 1042-7163
- DOI
- 10.1002/hc.20439
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β¦ Synopsis
Abstract
The effect of nucleophilic catalysis on phosphorus trichloride oxygen oxidation is discovered. A number of nucleophilic catalysts for the phosphorus trichloride oxidation are found. Triethylamine, 4βdimethylaminopyridine (DMAP), and tetramethylurea are amongst them. Β© 2008 Wiley Periodicals, Inc. Heteroatom Chem 19:408β411, 2008; Published online in Wiley InterScience (www.interscience.wiley.com). DOI 10.1002/hc.20439
π SIMILAR VOLUMES
## Abstract Intensely coloured, extremely moisture sensitive complexes [VOCl~3~(L)] (L = pyridine, quinoline, Ph~3~PO, Ph~3~AsO, pyridine __N__βoxide), [VOCl~3~(L)~2~] (L = pyridine, Me~3~PO, pyridine __N__βoxide), [VOCl~3~(LβL)] [LβL = 2,2β²βbipyridyl, 1,10βphenanthroline, Ph~2~P(O)CH~2~P(O)Ph~2~,