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Nucleophilic attacks on carbon-nitrogen double bonds. 3. Diversity of mechanisms for the substitution of diarylimidoyl chlorides by amines in acetonitrile

✍ Scribed by Ta-Shma, Rachel; Rappoport, Zvi

Book ID: 127218732
Publisher: American Chemical Society
Year: 1976
Tongue: English
Weight: 937 KB
Volume: 98
Category: Article
ISSN: 0002-7863
DOI: 10.1021/ja00442a024

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While several substitution meohauisms of 8 leaving group attoohed to a ;CX: bond arelmown,' those at 8 ;c?r-bond were little etudied. The kinetios of the hydrolyeis of the -C(Cl)=lF system was studied only by Ugi\* =d that of the -C(X)\*-lV-system by Soott end ooworkers.3 Intermediate nitrilium hali