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Nucleophilic Attack on the 2,5-Bis(perfluoroalkyl)-1,3,4-oxadiazoles. II. Synthesis of Perfluoroalkyl-Substituted 1,2,4,5-Tetrazines, 1,2-Dihydro-1,2,4,5-tetrazines, and 4-Amino-1,2,4,4H-triazoles 1

✍ Scribed by Brown, Henry C.; Gisler, Henry J.; Cheng, Ming T.


Book ID
126161747
Publisher
American Chemical Society
Year
1966
Tongue
English
Weight
456 KB
Volume
31
Category
Article
ISSN
0022-3263

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✍ Arnaud Cutivet; Emmanuel Leroy; Eric Pasquinet; Didier Poullain πŸ“‚ Article πŸ“… 2008 πŸ› Elsevier Science 🌐 French βš– 114 KB

A one step synthesis of (di)alkylamino-substituted 1,2,4,5-tetrazines direct from 3,6-disubstituted-1,2-dihydro-1,2,4,5-tetrazine precursors is described. A comparative study revealed that the described method not only avoids the up-to-now required oxidation step but also lower reaction times and/or