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Nucleophilic attack on carbon monoxide in carbonyl phosphine complexes of rhodium(I) and ruthenium(II): a novel route to complexes of rhodium(-I)

โœ Scribed by Johnston, Gregory G.; Hommeltoft, Sven I.; Baird, Michael C.


Book ID
126435529
Publisher
American Chemical Society
Year
1989
Tongue
English
Weight
897 KB
Volume
8
Category
Article
ISSN
0276-7333

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๐Ÿ“œ SIMILAR VOLUMES


Reactions of cationic rhodium(I) carbony
โœ E. Wynne Evans; Mohammed B. H. Howlader; Mark T. Atlay ๐Ÿ“‚ Article ๐Ÿ“… 1994 ๐Ÿ› Springer ๐ŸŒ English โš– 322 KB

The rhodium(I) carbonyl compounds [-Rh(CO)L2] [BF4]. 89 (L = PPh 3 or AsPh3) react with the nucleophiles OMe-, RCOO-(R = Me, Et) under nitrogen to form [Rh(OR)(CO)L2] (1)-(2) and [Rh(OOCR)(CO)L23 (7)-(i0), respectively. Addition of [Rh(CO)2(PPh3)2]-[BF4] to OMe-under nitrogen produces [Rh(COOMe)-(CO