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Nucleophilic Aromatic Substitution Reactions of Chloroazines with Bisulfide (HS - ) and Polysulfides (S n 2- )

✍ Scribed by Lippa, K. A.; Roberts, A. L.


Book ID
127101020
Publisher
American Chemical Society
Year
2002
Tongue
English
Weight
154 KB
Volume
36
Category
Article
ISSN
0013-936X

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Aromatic nucleophilic substitution react
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The reactions of 2-chloroquinoxaline with anilines in ethanol are found to follow second order kinetics, first order in each reactant. The activation parameters determined, from the rate data at five different temperatures are found to be typical of bimolecular aromatic nucleophilic substitutions (S