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Nucleophilic addition to 1,2,2,6,6-pentamethyl-3,5-dimethylene-4-piperidone

✍ Scribed by A. M. Belostotskii; A. B. Shapiro

Publisher
Springer US
Year
1987
Tongue
English
Weight
486 KB
Volume
23
Category
Article
ISSN
0009-3122

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The reaction of (C 5 Me 5 ) 2 Si or (C 5 Me 5 )SiMe 3 with B 2 Cl 4 leads to the adducts (C 5 Me 5 )BǞBCl 2 SiCl 3 (5a) or (C 5 Me 5 )BǞBCl 3 (5b), in which the Lewis acids stabilize the boranediyl frag- [a] Anorganisch-