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Nucleophilic addition of N-lithioamides to π-arenechromium tricarbonyl complexes. Preparation of aniline derivatives

✍ Scribed by L. Keller; K. Times-Marshall; S. Behar; K. Richards

Book ID
104229401
Publisher
Elsevier Science
Year
1989
Tongue
French
Weight
241 KB
Volume
30
Category
Article
ISSN
0040-4039

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✦ Synopsis

A simple procedure for the preparation of aniline derivatives by the nucleophilic addition of nitrogen anions to x-(arene)chromium tricarbonyl complexes is described.

Despite its importance, the number of methods for the introduction of nitrogen-bearing functional groups onto an aromatic ring is quite limited. Furthermore, almost every standard method of nitrogen-to-arenecarbon bond formation requires either electrophilic attack by nitrogen (nitration, azobenzene formation, etc.) or the use of Hofmann/Curtius/Schmidt-like rearrangements.

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