Nucleophilic Activation of Alkenyl and Aryl Boronates by a Chiral CuIF Complex: Catalytic Enantioselective Alkenylation and Arylation of Aldehydes
β Scribed by Daisuke Tomita; Motomu Kanai; Masakatsu Shibasaki
- Book ID
- 112005123
- Publisher
- John Wiley and Sons
- Year
- 2006
- Tongue
- English
- Weight
- 238 KB
- Volume
- 1
- Category
- Article
- ISSN
- 1861-4728
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## Abstract For Abstract see ChemInform Abstract in Full Text.
Ligand exchange reaction of I~-mesyloxy sulfoxides or 13-acetoxy sulfoxides, which were derived from alkenyl aryl sulfoxides and aldehydes in two steps, with n-BuLi or EtMgBr at low temperature gave allenes in good yields. Optically active allenes were synthesized starting from optically active 2-ph
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