The energy levels due to the motion of the ammonium ion in the ordered phase of ammonium chloride are computed by diagonalizing the Hamiltonian matrices. These computed energy levels are in good agreement with the lower four anharmonic levels observed by neutron inelastic incoherent scattering, Rama
โฆ LIBER โฆ
Nucleation of ammonium chloride in the gas phase and the influence of ions
โ Scribed by Banic, C. M.; Iribarne, J. V.
- Book ID
- 119718960
- Publisher
- American Geophysical Union
- Year
- 1980
- Tongue
- English
- Weight
- 570 KB
- Volume
- 85
- Category
- Article
- ISSN
- 0148-0227
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The barriers to rotation for the ammonium ion in the ordered and disordered phases of ammonium chloride and amm&ium bromide are calculated from their torsional frequencies. The results are comparec! to the activation energies determined from NMR results.