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Nucleation behavior of sheared poly(ethylene oxide) melts

✍ Scribed by Robert D. Ulrich; Fraser P. Price

Publisher: John Wiley and Sons
Year: 1976
Tongue: English
Weight: 587 KB
Volume: 20
Category: Article
ISSN: 0021-8995
DOI: 10.1002/app.1976.070200420

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✦ Synopsis

The nucleation behavior of a poly(ethy1ene oxide) melt is measured as the material crystallizes under defined conditions of shear and temperature. Polarized light microscopy is used as the measuring technique. A strong dependence of nucleation rate on supercooling and imposed stress was found. This behavior is explained in terms of stress-induced supercooling of melts. A correlation between the nucleation behavior and morphology of the sheared material is attempted.

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