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Nuclear spin relaxation in hydrogen: I. The gas

โœ Scribed by Myer Bloom


Publisher
Elsevier Science
Year
1957
Weight
563 KB
Volume
23
Category
Article
ISSN
0031-8914

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โœฆ Synopsis


The proton spin-lattice relaxation time tl has been measured in H2 gas as a function of (a) density at 20.4ยฐK, (b) ortho-para concentration at 20.4ยฐK, (c) percentage H2 molecules in H~-He mixtures at 20.4ยฐK, (d) density of the saturated vapour between 20.4ยฐK . and 15:5ยฐK. The results are interpreted in terms of the relaxation mechanism originally proposed by Schwinger and provide a measurement of the cross section for collisions which cause the ortho-H2 molecules to reorient. The average cross section for collisions which produce reorientations is three times as high for ortho-ortho collisions as for ortho-para collisions at 20.4ยฐK. The effective cross section rises rapidly with decreasing temperature. It is suggested that tl measurements will enable a detailed study of the anisotropic part of the H2-H2 and Ho~-He interactions to be made. The proton tl in HD is much longer than that of the protons in H~ because the ground state of HD is J = 0 where the Schwinger mechanism is inoperative. One can infer the mean time spent by HD molecules in the J -1 state from tl measurements.


๐Ÿ“œ SIMILAR VOLUMES


Nuclear spin relaxation in hydrogen: II.
โœ Myer Bloom ๐Ÿ“‚ Article ๐Ÿ“… 1957 ๐Ÿ› Elsevier Science โš– 507 KB

The proton spin relaxation time tl for H2 liquid has been measured as a function of temperature and otho-para concentration. For normal H2, tx is found to be 0.18 second at 20.4ยฐK and is found to increase with decreasing temperature and decrease with decreasing ortho-H2 concentrations. Calculations