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Nuclear spin and inversion state selection of NH3 via molecular beam electric deflection

✍ Scribed by Bruce D. Kay; T.D. Raymond


Book ID
103025658
Publisher
Elsevier Science
Year
1986
Tongue
English
Weight
393 KB
Volume
127
Category
Article
ISSN
0009-2614

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✦ Synopsis


A nuclear-spin and inversion state-selected NH, beam is produced by coupling molecular beam electnc deflection techniques with the extreme rotational cooling of a pulsed supersonic expansion. Two-photon resonant three-photon ionization is used to probe the molecular beam quantum state distribution.

The resulting beam is predominantly ( > 95%) in a single quantum state (neglecting hyperfine structure), namely JK = l,, m the upper inversion state with para nuclear spin symmetry.