✦ LIBER ✦
Nuclear Quadrupole Resonance and Stereochemistry II. Vicinal cis- and trans-dichloro derivatives of carbocyclic systems
✍ Scribed by Ziba Ardalan; Edwin A. C. Lucken; S. Masson
- Book ID
- 102251436
- Publisher
- John Wiley and Sons
- Year
- 1973
- Tongue
- German
- Weight
- 313 KB
- Volume
- 56
- Category
- Article
- ISSN
- 0018-019X
No coin nor oath required. For personal study only.
✦ Synopsis
Abstract
The ^35^Cl quadrupole resonance frequencies of sets of isomeric vicinal dichloro derivatives of carbocyclic molecules are presented. In all cases except one – cis‐ and trans‐1, 2‐dichloro‐acenaphthene – the configuration has only a small effect on the resonance frequency. This implies that the frequency‐differences in cyclic α‐chloroethers reported in Part I of this series [1] are indeed due to a specific interaction with the oxygen atom. The difference between the acenaphthenes may be due to hyperconjugation between the CCl bond and the aromatic system.