Nuclear quadrupole coupling in Cu(C2O4)2 dianion

✍ Scribed by Lawrence K. White; R.Linn Belford

• Publisher: Elsevier Science
• Year: 1976
• Tongue: English
• Weight: 290 KB
• Volume: 37
• Category: Article
• ISSN: 0009-2614
• DOI: 10.1016/0009-2614(76)85036-1

✦ Synopsis

Rekved II August i97.5 5~ measurement of' the angulltr deFndence of wparriticjns between pairs of forbidden @MJ + 0) lines in Q-band EPR spectra, the nuclcnr quadnzpole wupling paranxcrcr QD is dctermincd to be + (4.5 I 0.2) X IO-" cm -' Par 63Cu doped into iC2Pd(C20~)2.2H2Ci. Tne increase of=; 1.2 X lOA cm-' over the related copper p_ketocnolates is quantitatively nccounted for by the expected reduction of dn-lipand bsckbondiM.