Nuclear Overhauser effect, a unique method of defining the relative stereochemistry and conformation of taxane derivatives
β Scribed by Woods, Marion C.; Chiang, Hung-Che.; Nakadaira, Yasuhiro.; Nakanishi, Koji.
- Book ID
- 126801547
- Publisher
- American Chemical Society
- Year
- 1968
- Tongue
- English
- Weight
- 276 KB
- Volume
- 90
- Category
- Article
- ISSN
- 0002-7863
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π SIMILAR VOLUMES
The configurations of some isoxazolidinium salts have been determined by nuclear Overhauser effect difference spectroscopy (NOEDS). The stereochemical findings give a good explanation of the different reactivities experienced in the five-membered ring-opening process as a function of the steric requ
The study of 5-f~ctionalized 2-imidazolines by 'β¬I NMR, l -D NOE and 2-D NOE is reported. The application of these methods con6rms the relative configurations and conformations of the compounds. In particular, NOE effects and related crystallographic data are in good agreement with the proposed angu