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Nuclear magnetic resonance study of thiophen-2-carboxaldehyde and thiophen-2,5-dicarboxaldehyde in a lyotropic mesophase. Molecular structure and orientation

✍ Scribed by A. Amanzi; D. Silvestri; C.A. Veracini; P.L. Barili


Publisher
Elsevier Science
Year
1977
Tongue
English
Weight
313 KB
Volume
51
Category
Article
ISSN
0009-2614

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✦ Synopsis


The proton magnetic resonance spectra of thiophen-Z-carboxaldehyde and thiophen-2,5slicarboxaldehyde, partially oriented in anisotropic soap solutions have been recorded and analyzed. Comparisons of results obtained here and in previous Work based on the use of thermotropic media are presented.


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## Abstract The ^1^H NMR spectra of imidazo [1,2‐__a__]pyrimidine derivatives have been analysed to study the aromatic character and protonation behaviour of this system. By employing the β€˜ring currentn’ model and calculations based on the coupled Hartree‐Fock method it can be deduced that a large