Nuclear magnetic resonance study of hydrogen mobility in LaY2Ni9Hx and CeY2Ni9Hx
β Scribed by A.V. Soloninin; A.L. Buzlukov; A.V. Skripov; M. Latroche; V. Paul-Boncour
- Book ID
- 104030293
- Publisher
- Elsevier Science
- Year
- 2009
- Tongue
- English
- Weight
- 737 KB
- Volume
- 182
- Category
- Article
- ISSN
- 0022-4596
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β¦ Synopsis
In order to investigate the mobility of hydrogen in the ternary compounds LaY 2 Ni 9 and CeY 2 Ni 9 , we have measured the proton nuclear magnetic resonance (NMR) spectra and the proton spin-lattice relaxation rates R 1 for LaY 2 Ni 9 H x (x ΒΌ 0.78 and 10.3) and CeY 2 Ni 9 H x (x ΒΌ 0.79 and 7.2). The measurements have been performed at the resonance frequencies of 14, 23.8 and 90 MHz over the temperature range of 11-404 K. For LaY 2 Ni 9 H x , the behavior of R 1 is consistent with the presence of a considerable contribution due to motionally modulated dipole-dipole interaction between nuclear spins. This contribution can be satisfactorily described in terms of the Bloembergen-Purcell-Pound model with a Gaussian distribution of activation energies for hydrogen diffusion; the value of the average activation energy resulting from such a description for LaY 2 Ni 9 H 10.3 is approximately 0.36 eV. For CeY 2 Ni 9 H x compounds, the measured proton spin-lattice relaxation rates are dominated by the contribution due to the interaction between proton spins and paramagnetic centers over the entire temperature range studied. Only qualitative information on H mobility in these compounds has been obtained from the narrowing of NMR spectra. Possible paths of H diffusion in LaY 2 Ni 9 H x and CeY 2 Ni 9 H x are discussed in terms of the distances between the interstitial sites occupied by hydrogen.
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