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Nuclear magnetic resonance studies of a radical-radical dimerization reaction

✍ Scribed by Williams, David James.; Kreilick, Robert W.

Book ID
127353962
Publisher
American Chemical Society
Year
1967
Tongue
English
Weight
510 KB
Volume
89
Category
Article
ISSN
0002-7863

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1H nuclear magnetic resonance studies of
1H nuclear magnetic resonance studies of the reaction of iron(III) porphyrin cation radical with aryl Grignard reagents
✍ Piotr J. Chmielewski; Lechoslaw Latos-graΕΌyΕ„ski; Krystyna Rachlewicz πŸ“‚ Article πŸ“… 1993 πŸ› John Wiley and Sons 🌐 English βš– 583 KB

## Abstract Addition of aryl Grignard reagents to an iron(III) tetraphenylporphyrin Ο€ cation radical, [(TPPβ‹…)Fe^III^Cl] (SbCl~6~), in dichloromethane solution at 202 K yields a mixture of σ‐phenyl iron(IV) tetraphenylporphyrin, [(TPP)Fe^IV^(Ph)] (SbCl~6~), and σ‐phenyl iron(III) tetraphenylporphyri