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Nuclear magnetic resonance studies of 35Cl, 37Cl, 79Br and 81Br

✍ Scribed by J. Blaser; O. Lutz; W. Steinkilberg

Publisher
Elsevier Science
Year
1970
Tongue
English
Weight
156 KB
Volume
32
Category
Article
ISSN
0375-9601

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## Abstract Long‐range isotope shifts, Δδ, due to ^37^Cl/^35^Cl and ^81^Br/^79^Br, in the ^19^F NMR spectra of some substituted benzenes are reported. The shifts appear to be invariant to solvent and are additive when the isotopes are in chemically equivalent positions relative to the fluorine site

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The nuclear hyperfine structure m the J= 1 +O transItions of the four lsotopomers 79Br3sC1, 79Br37Cl, 81Bti3'C1 and "'B?'Cl has been observed m the mbrational states u=O and u= 1 by pulsed-nozzle, Founer-transform microwave spectroscopy Accurate values of the nuclear quadrupole coupling constants XL