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Nuclear magnetic resonance spectroscopy. Slow nitrogen inversion in an acyclic substituted hydrazine

✍ Scribed by Anderson, James Edgar; Griffith, Dean L.; Roberts, John D.

Book ID
126334263
Publisher
American Chemical Society
Year
1969
Tongue
English
Weight
354 KB
Volume
91
Category
Article
ISSN
0002-7863

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Nitrogen-15 nuclear magnetic resonance s
Nitrogen-15 nuclear magnetic resonance spectroscopy. Differential rates of NH proton-exchange reactions of hydrazine-carbothioamide and 4-methylhydrazine-carbothioamide in dimethyl sulfoxide
✍ Issa Yavari; John D. Roberts 📂 Article 📅 1980 🏛 John Wiley and Sons 🌐 English ⚖ 344 KB

## Abstract The proton‐coupled nitrogen‐15 NMR spectra of hydrazinecarbothioamide and 4‐methylhydrazinecarbothioamide have been taken at the natural‐abundance level in neutral, basic and acidic solutions at 25°C. The NH proton‐exchange reactions of the hydrazino‐NH~2~ groups in both compounds were