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Nuclear magnetic resonance spectrometry of naturally occurring polyprenols

✍ Scribed by J. Feeney; F.W. Hemming

Publisher
Elsevier Science
Year
1967
Tongue
English
Weight
788 KB
Volume
20
Category
Article
ISSN
0003-2697

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✦ Synopsis

h number of alcohols with the general formula I, where 7~ = 1 to 13, occur in nature. Green leaves of many higher plant,s yield polyprenols (structure I) in which TL = 9 to 13 (l-4), while the wood of the silver hircsh contains polyprenols with from 6 to 9 isoprene residues (1, 5, 6). A series of alcohols in which n = 16 to 21 and in which the OH-terminal koprene residue is saturated (Structure II) have been isolated from mammalian tissues and have heru termed dolichols (1, 7). Similar alcohols ill \-hich n varies from 14 to 18 have been isolat'ed from bakers' yeast (1, 8). Finally, the mould Aspergillus jumigatus Fresenius has been shown to contain a family of hexahydropolyprenols (Structure III) containing 18 to 24 imprem FEENEY AND HEMMING

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