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Nuclear magnetic resonance proton dynamics study of [N(CH3)2H2]3Bi2I9 at low temperature

✍ Scribed by N. Piślewski; J. Tritt-Goc; R. Jakubas

Publisher
Elsevier Science
Year
1995
Tongue
English
Weight
249 KB
Volume
4
Category
Article
ISSN
0926-2040

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✍ A.L. Barra; Andrea Caneschi; Dante Gatteschi; David P. Goldberg; Roberta Sessoli 📂 Article 📅 1999 🏛 Elsevier Science 🌐 English ⚖ 134 KB

The high-5eld EPR spectra of a mixed valence cluster compound of formula [Et 3 NH] 2 [Mn(CH 3 CN) 4 (H 2 O) 2 ] [Mn 10 O 4 (biphen) 4 Br 12 ] con5rm that the high-spin ground state (S ‫؍‬ 12) of the cluster has a negative zero-5eld splitting, D ‫؊؍‬ 0.037(1) cm ؊1 . The reversal of the magnetization