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Nuclear magnetic resonance properties of tellurium dichloride derivatives of methyl telluralaurate isomers

✍ Scribed by Marcel S.F. Lie Ken Jie; Sherman H. Chau

Publisher
Elsevier Science
Year
1995
Tongue
English
Weight
210 KB
Volume
78
Category
Article
ISSN
0009-3084

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✦ Synopsis

Reaction of methyl 2-to 6-telluralaurate with sulfuryl chloride gives the corresponding tellurium dichloride (TeC12) derivatives quantitatively. The TeC12 group induces a strong de-shielding effect on the adjacent methylene groups. The 2-, 3-and 4-positional isomers are identified by ~H-NMR spectroscopic analysis, and ~3C-NMR spectroscopic analysis allows all five positional isomers to be characterized.

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