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Nuclear magnetic resonance investigation of geometrical isomerism in the anions of (methylamino) pyridines. Assignment of the syn and anti isomers

โœ Scribed by Kos, Nico J.; Breuker, Koos; Van der Plas, Henk C.; Van Veldhuizen, Beb


Book ID
127065638
Publisher
American Chemical Society
Year
1981
Tongue
English
Weight
399 KB
Volume
46
Category
Article
ISSN
0022-3263

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The anti-syn interconversion rate of (p-Buts),-Fe,(CO), is about one thousand times faster than that of the other alkyl and aryl derivatives and becomes fast in the NMR time scale at temperatures above 90 'C. The coalescence temperature of the But signals is lowered by substitution of a carbonyl gro