Nuclear magnetic resonance in pulse radiolysis. Chemically induced dynamic nuclear polarization
โ Scribed by Trifunac, A. D.; Johnson, K. W.; Lowers, R. H.
- Book ID
- 121326793
- Publisher
- American Chemical Society
- Year
- 1976
- Tongue
- English
- Weight
- 262 KB
- Volume
- 98
- Category
- Article
- ISSN
- 0002-7863
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๐ SIMILAR VOLUMES
A simple method is developed for calculation of nuclear polarization in products of radical coupling reactions carried out at zero magnetic field. The theory of chemically induced dy\_~ic nuclear polarization (CIDNP) has received considerable attention from several authors [l-4].
CJDNP cffccts durmg bcnzoyl peroxide thermolysis have been measured duectly by a pulsed NMR spectrometer in Jaw magnetic fields (OS-120 Oe). It IF shown tilat the traditional technique of the sample "transfer" distorts the real magnetic ticld dcpendsncc of CJDNP.