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Nuclear and Magnetic Structure of U3Ga2Ge3: A Neutron Powder Diffraction Study

✍ Scribed by Peter Rogl; Gilles André; Franz Weitzer; Michel Potel; Henri Noël


Publisher
Elsevier Science
Year
1997
Tongue
English
Weight
327 KB
Volume
131
Category
Article
ISSN
0022-4596

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✦ Synopsis


The crystal structure of U 3 Ga 2 Ge 3 has been investigated by means of neutron powder diffractometry in the range from 1.5 to 100 K. Full matrix full profile refinements of the nuclear structure at 100 K revealed a new structure type with almost fully ordered distribution of Ga and Ge atoms in the 8c sites of space group I4. The new U 3 Ga 2 Ge 3 type is a low symmetry derivative of the ordered antitype-Cr 5 B 3 (I4/mcm), R I ‫؍‬ 0.032, R F ‫؍‬ 0.030. From model refinements, eventual interstitial nonmetal occupation in the metal octahedra U 1 Ge 1 Ge 2 Ga 2 or U 2 Ge 2 Ga 2 or in metal tetrahedra Ge 2 Ga 2 is ruled out. At temperatures lower than T c ‫؍‬ 90 K uranium atoms order ferromagnetically as monitored by the intensity of the magnetic reflection M I (011) . Due to the observation of the M (011) reflection, the magnetic spin structure is consistent with the symmetry of the noncentrosymmetric space group I422. The lower symmetry invokes a splitting of the 4a sites of the parent Cr 5 B 3 type (I4/mcm) into two twofold uranium sites 2a and 2b of I422. Besides the uranium atoms in 8j ( U ‫؍‬ 2.57 B ), only the uranium atoms in 2a were found to carry a magnetic moment U ‫؍‬ 2.45 B . All moments are parallel to the crystallographic a axis. To comply with the symmetry of the Ge/Ga atoms, magnetic and nuclear structure have to be described in space group I4. The reliability values for the 1.5 K diffractogram were: R I ‫؍‬ 0.024, R F ‫؍‬ 0.019, and R mag ‫؍‬ 0.033.


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