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N,P-Organometall-phosphinimine aus Aminophosphinen

✍ Scribed by Priv.-Doz. Dr. O. J. Scherer; cand. chem. G. Schieder


Publisher
John Wiley and Sons
Year
1968
Tongue
English
Weight
198 KB
Volume
80
Category
Article
ISSN
0044-8249

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Untersuchungen an der PN-Doppelbindung,
✍ Wiegräbe, Winfried ;Bock, Hans 📂 Article 📅 1968 🏛 Wiley (John Wiley & Sons) 🌐 English ⚖ 731 KB

Dabei ergibt sich, daB polare Anteile >? -N--offenbar die PN-Bindungsordnung erhohen. ' 5 W Bei Versuchen, Additions-Reaktionen an Phosphiniminen X2Y P =N ~ Z nachzuweisen\*.3~, hatte sich gezeigt, dal3 vor allem Stickstoff-Substituenten Z die P-N-Doppelbindung erheblich beeinflussen konnen. Zum wei

New Organometallic Palladium(II) Complex
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New neutral organometallic palladium(II) complexes, obtained upon treating complexes of the type [PdRX(P ʝ N)] with PPh 3 and AgCF 3 SO 3 and consist predominantly of the [PdPhI(PNMe 2 )] (1), [PdPhI(PC=NMe)] (2), [PdPhI(PC=NEt)] (3), and [PdMeCl(PNMe 2 )] (4), {PNMe 2 means N,N-dimethyl-trans-P,P i