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Novel Vanadium(V) Compounds with a Layer Structure: Synthesis, Crystal Structures, and Solid State NMR Spectroscopy of [(VO 2 ) 2 (4,4‘-bpy) 0.5 (4,4‘-Hbpy)(XO 4 )]·H 2 O (X = P and As)

✍ Scribed by Huang, Li-Hsun; Kao, Hsien-Ming; Lii, Kwang-Hwa


Book ID
125968216
Publisher
American Chemical Society
Year
2002
Tongue
English
Weight
146 KB
Volume
41
Category
Article
ISSN
0020-1669

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A new zinc phosphate, (C 10 N 4 H 28 )[Zn 6 (HPO 4 ) 2 (PO 4 ) 4 ] ' 2H 2 O, with a layered architecture has been synthesized, for the 5rst time, in the presence of 1,4-bis(3-aminopropyl)piperazine as the structure-directing agent. The structure comprises a network of ZnO 4 and phosphate tetrahedra