Novel Transition-Metal (M=Cr, Mo, W, Fe) Carbonyl Complexes with Bis(guanidinato)silicon( II ) Ligands
✍ Scribed by Mück, Felix M.; Kloß, Dorit; Baus, Johannes A.; Burschka, Christian; Tacke, Reinhold
- Book ID
- 125854548
- Publisher
- John Wiley and Sons
- Year
- 2014
- Tongue
- English
- Weight
- 425 KB
- Volume
- 20
- Category
- Article
- ISSN
- 0947-6539
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📜 SIMILAR VOLUMES
phosphorus (3Jc-p = 6.2 and 5.7 Hz, respectively) indicating an antiperiplanar conformation of the C-S-C-P fragment and hence the prevailing equatorial position of the triphenylphosphonium group in solution. The y-effect values (+ 0.135 and -0.26 for 3 and 4, respectively) are also in accord with th
Quantum mechanical ab initio calculations at the MP2 and CCSD(T) level of theory have been used to investigate the geometries and bond energies of the complexes M(CO) 6±x (H 2 ) x (M = Cr, Mo, W; x = 1, 2, 3). The theoretically predicted M(CO) 5 ±(H 2 ) bond dissociation energies are in excellent ag