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Novel tocopherol compounds I. Bromination of α-tocopherol — reaction mechanism and synthetic applications

✍ Scribed by T. Rosenau; W.D. Habicher

Book ID
107857590
Publisher
Elsevier Science
Year
1995
Tongue
French
Weight
536 KB
Volume
51
Category
Article
ISSN
0040-4020

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A novel mechanism for the formation of 5,6-tocopheryldione (~t-tocored, 4) from c~-tocopherol (vitamin E, l) has been established. The reaction has been shown to proceed via a 5-alkoxytocopherol intermediate, with cleavage of the 5a-methyl group as methanol, contrary to results reported so far in th