Novel Synthetic Methodologies. Part 106. Efficient Regio- and Stereoselective Conversions of Oxiranes and Aziridines into β-(Nitrooxy)-Substituted Alcohols and Amines by Using Bismuth Nitrate.

Efficient Regio- and Stereoselective Con

Efficient Regio- and Stereoselective Conversions of Oxiranes and Aziridines into β-(Nitrooxy)-Substituted Alcohols and Amines by Using Bismuth Nitrate

✍ Biswanath Das; Maddeboina Krishnaiah; Katta Venkateswarlu; Vtukuri Saidi Reddy 📂 Article 📅 2007 🏛 John Wiley and Sons 🌐 German ⚖ 69 KB

Oxiranes and aziridines efficiently undergo ring opening with bismuth nitrate at room temperature to furnish the corresponding b-(nitrooxy)-substituted alcohols and amines respectively. The conversions are highly regio-and stereoselective and afford the nitrooxy-compounds in excellent yields within