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Novel Synthesis of Naphthobenzazepines from N-Bromobenzylnaphthylamines by Regioselective C—H Activation Utilizing the Intramolecular Coordination of an Amine to Pd.

✍ Scribed by Takashi Harayama; Tomonori Sato; Akihiro Hori; Hitoshi Abe; Yasuo Takeuchi

Publisher: John Wiley and Sons
Year: 2003
Weight: 154 KB
Volume: 34
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.200341165

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## Abstract Electron‐withdrawing substituents in the meta position of the aniline moiety and any position of the pyridine ring are unfavorable in this reaction.