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Novel Synthesis of (Butatriene)hexacarbonyldiiron Complexes. Stereochemical Aspects and an X-ray Crystal Structure Determination.

✍ Scribed by Eigemann, Sven-Eric; Förtsch, Walter; Hampel, Frank; Schobert, Rainer


Book ID
126830427
Publisher
American Chemical Society
Year
1996
Tongue
English
Weight
16 KB
Volume
15
Category
Article
ISSN
0276-7333

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The synthesis and X-ray crystal structure determination of a novel metal-terphenyl derivative, namely DmpAuPPh 3 (1), is reported (Dmp = 2,6-dimesitylphenyl). Complex 1 is synthesized by the reaction of one equivalent of DmpLi with one equivalent of Ph 3 PAuCl in tetrahydrofuran at room temperature