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Novel Synthesis of 5-(Arylimino)-4-(dialkylamino)-5H-1,2,3-dithiazoles and the Mechanism of Their Formation

โœ Scribed by Lee, Hyunil; Kim, Kyongtae; Whang, Dongmok; Kim, Kimoon


Book ID
121500752
Publisher
American Chemical Society
Year
1994
Tongue
English
Weight
601 KB
Volume
59
Category
Article
ISSN
0022-3263

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Synthesis of new5-alkylidene-4-chloro-5H
โœ Moon-Kook Jeon; Kyongtae Kim ๐Ÿ“‚ Article ๐Ÿ“… 1999 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 948 KB

A variety of 5-alkylidene-4-chloro-5H-I,2,3-dithiazoles (9-25) have been prepared from 4chloro-5H-l,2,3-dithiazolium chloride, active methylene compounds, and pyridine. The reactions with ethyl nitroacetate ((Z) > (E)), ethyl 3-nitrobenzoylacetate ((E) > (Z)), ethyl 2-fluorobenzoylacetate ((E) > (Z)