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Novel synthesis of 2-amino[1,4,5]benzoxadiazepine derivatives via a mild one-pot reaction

✍ Scribed by Eman A. El-Rady


Publisher
Journal of Heterocyclic Chemistry
Year
2002
Tongue
English
Weight
32 KB
Volume
39
Category
Article
ISSN
0022-152X

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✦ Synopsis


Abstract

The diazonium salt of 2‐aminophenol 2 was coupled in situ with malononitrile derivatives 3a‐d, 2‐cyanomethylthiazolin‐4‐one 9, 2‐cyanomethylbenzimidazole 11a, and 2‐cyanomethylbenzothiazole 11b to give 2‐amino[1,4,5]benzoxadiazepine derivatives 6a‐d, 10 and 12a,b via a one‐pot reaction.


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