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Novel sulfur-containing ferrocene polymers

✍ Scribed by Oskar Nuyken; Thomas Pöhlmann; Max Herberhold

Publisher
John Wiley and Sons
Year
1996
Tongue
English
Weight
544 KB
Volume
197
Category
Article
ISSN
1022-1352

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✦ Synopsis

Abstract

Ferrocene‐containing polymers were synthesized via addition reaction of 1,1′‐dimercaptoferrocene (1) and 1,1′‐bis(2‐mercaptoethyl)ferrocene (2) to various diolefinic monomers such as dimethacrylates, divinyl ethers, divinyl sulfones and others. The dithiol 1 was also used as a monomer in condensation reactions with bifunctional acid chlorides. The polymerization of propylene sulfide in the presence of 1 as a bifunctional initiator was found to lead to polymers with a single central ferrocene unit.

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