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Novel sulfonylpolystyrene-supported prolinamides as catalysts for enantioselective aldol reaction in water

✍ Scribed by Pedrosa, Rafael; Andrés, José M.; Gamarra, Ana; Manzano, Rubén; Pérez-López, César

Book ID: 121447827
Publisher: Elsevier Science
Year: 2013
Tongue: French
Weight: 488 KB
Volume: 69
Category: Article
ISSN: 0040-4020
DOI: 10.1016/j.tet.2013.10.093

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## Abstract A solvent‐free asymmetric and direct __anti__‐aldol reaction of aliphatic ketones with aromatic aldehydes catalyzed by recyclable L‐prolineamides and L‐prolinethioamides **3** is studied. The L‐prolinethioamide **3d** (5 mol%), derived from L‐Pro and (__R__)‐1‐aminoindane, is the most e