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Novel stereoselective synthesis of 1,3-dienes from alkynes via the addition of cuprous chloride to vinylalanes

✍ Scribed by Zweifel, George.; Miller, Robert L.


Book ID
125940553
Publisher
American Chemical Society
Year
1970
Tongue
English
Weight
271 KB
Volume
92
Category
Article
ISSN
0002-7863

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ChemInform Abstract: Novel Two-Step Ster
✍ H. DOUCET; C. BRUNEAU; P. H. DIXNEUF 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 31 KB 👁 2 views

Novel Two-Step Stereoselective Synthesis of (E)-Enamines and 1-Amino-1, 3-dienes from Terminal Alkynes. -The two-step synthesis of (E)-enamines and 1-amino-1,3-dienes is accomplished by regio-and stereoselective Ru-catalyzed addition of acetic acid to alkynes (I). The resulting acetates react with