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Novel ring-closing reactions in thermolyses of 2-methylene-1,3,4-thiadiazoline derivatives

✍ Scribed by Toshiya Furuhata; Wataru Ando

Publisher: Elsevier Science
Year: 1987
Tongue: French
Weight: 235 KB
Volume: 28
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(00)95320-6

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✦ Synopsis

Thermal decomposition of 2-methylene-1,3,4_thiadiazoline derivatives produced allene episulfide, benzothiophene, and divinyl sulfide derivatives via 1,3-and 1,5-diradical or thioxyallyl intermediate.

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