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Novel Rhodium-Catalyzed Reaction of Thiazolidine Derivatives with Carbodiimides

✍ Scribed by Hai-Bing Zhou; Chune Dong; Howard Alper

Publisher
John Wiley and Sons
Year
2004
Tongue
English
Weight
297 KB
Volume
10
Category
Article
ISSN
0947-6539

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✦ Synopsis

Abstract

A new, simple, and regioselective synthesis of thiazolidinimine derivatives based on the rhodium‐catalyzed reaction of readily available thiazolidines with carbodiimides is described. This methodology provides direct access to a large variety of thiazolidinimine derivatives, possibly via a novel regiospecific insertion of carbodiimides into one of two ring carbon–nitrogen bonds, as well as a metal‐catalyzed imine elimination process.

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