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Novel regioselective chlorination of aliphatic ketones via mono-organothallium(III) derivatives

โœ Scribed by Glaser, Julius; Toth, Imre

Book ID
120794986
Publisher
The Royal Society of Chemistry
Year
1986
Tongue
English
Weight
188 KB
Volume
17
Category
Article
ISSN
0022-4936

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Thallium in organic synthesis. 47. Regio
Thallium in organic synthesis. 47. Regioselective ring expansion of cyclic aralkyl ketones via wittig-derived olefins with thallium(III) nitrate (TTN)
โœ Edward C. Taylor; Chih-Shu Chiang; Alexander McKillop ๐Ÿ“‚ Article ๐Ÿ“… 1977 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 222 KB

We have recently described 3-5 a number of TTN-mediated oxidations of styrene derivatives which proceed extremely rapidly at room temperature to give high yields of carbonyl compounds. The overall transformation is